Title page for ETD etd-05112006-154831

Type of Document Dissertation
Author Liu, Yanjing
URN etd-05112006-154831
Title Characterization and patterned polymer films from a novel self-assembly process
Degree PhD
Department Chemistry
Advisory Committee
Advisor Name Title
Schick, G. Alan Committee Chair
Anderson, Mark R. Committee Member
Desu, Seshu B. Committee Member
Schug, John C. Committee Member
Wightman, James P. Committee Member
  • Self-Assembly
  • Photolithography
  • Organic Thin Films
  • Muitilayers
  • Pattern
Date of Defense 1996-05-03
Availability restricted

The layer-by-layer molecular-level manipulation of ionic polymer have been utilized to fabricate ultrathin multilayer films (SAMp). In this process, monolayers of polycations and polyanions are sequentially adsorbed onto a substrate surface by alternately dipping the substrate into aqueous solutions of poly(vinylamine) backbone azo (PDYE), poly(sodium 4-styrenesulfonate) (PSS), and poly(al1ylamine hydrochloride) (PAH). The ionic attractions developed between the oppositely charged polymers promote strong interlayer adhesion and a uniform and linear multilayer deposition process. UV Vis absorbance, contact angle, and ellipsometry measurements revealed that in all cases the bilayer deposition process was linear and highly producible from layer to layer and film thickness of up to 1 µm can be easily obtained by repeating the deposition process. The typical thickness of bilayer film depend on the solution concentration. Contact angle and UV Vis spectroscopy measurements demonstrated that the deposition time for a full monolayer coverage of azo dye and PAH was about 20 seconds. Our results showed that the mechanical stability of these SAMp films was remarkable, and SAMp films can only be removed from the substrate by scraping. SAMp films are stable in the common organic solvents and even in the high acidic media (6M Hel aqueous solution). The conformation of these films are thermlly stable at high temperature.

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