Title page for ETD etd-08252008-162325

Type of Document Dissertation
Author Greene, James Carson
URN etd-08252008-162325
Title A study of the displacement of halogen from chlorinated heteroaromatic azines by dialkali salts of benzoylacetone, disodio salts of certain 2-hydroxy-4-methylpyrimidines, and the methylsulfinyl carbanion
Degree PhD
Department Chemistry
Advisory Committee
Advisor Name Title
Wolfe, James F. Committee Chair
Clifford, Alan F. Committee Member
Dillard, John G. Committee Member
Ogliaruso, Michael A. Committee Member
Ward, Thomas C. Committee Member
  • nucleophilic substitution reaction mechanisms
Date of Defense 1971-11-01
Availability unrestricted

Halogenated monocyclic and bicyclic heteroaromatic azines, possessing a six or ten w-electron system and one or two ring nitrogens, have been shown to undergo nucleophilic displacement of halide ion with a variety of nucleophiles. A detailed review of the relative reactivity of compounds of these classes, as well as halogenated heteroaromatic azines containing as many as four nitrogen atoms has appeared.

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