Title page for ETD etd-11302012-040014

Type of Document Dissertation
Author Carver, David Reginald
URN etd-11302012-040014
Title The SRN1 reactivity of selected aromatic diazines
Degree PhD
Department Chemistry
Advisory Committee
Advisor Name Title
Wolfe, James F. Committee Chair
Bell, Harold M. Committee Member
Hudlicky, M. Committee Member
Sanzone, George Committee Member
Taylor, Larry T. Committee Member
  • Substitution reactions
Date of Defense 1979-08-05
Availability restricted

The scope and limitations of aromatic diazines undergoing nucleophilic substitution reactions occurring via a radical-chain (SRN1) mechanism were investigated. The study was conducted on a series of mono- and dihalogenated aromatic diazines interacting with various ketone enolates in ammonia. Results indicate that this previously unrecognized reaction pathway in these nitrogen heterocycles is easily obtained and should prove of great synthetic utility in preparation of substituted diazines.

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