Title page for ETD etd-12212003-204524

Type of Document Dissertation
Author Morton, Siyuan Chen
URN etd-12212003-204524
Title Phosphorus in the Environment and its Role in Anaerobic Iron Corrosion
Degree PhD
Department Environmental Engineering
Advisory Committee
Advisor Name Title
Edwards, Marc A. Committee Chair
Corcoran, Sean Gerald Committee Member
Little, John C. Committee Member
Love, Nancy G. Committee Member
Rimstidt, james Donald Committee Member
  • Reduced Phosphorus
  • Phosphorus Analysis
  • Anaerobic Iron Corrosion
Date of Defense 2003-11-19
Availability unrestricted
Phosphorus chemistry controls key aspects of eutrophication, microbial nutrition, corrosion and other environmental processes. It is commonly assumed that phosphorus occurs exclusively as phosphate (+5) in nature. In fact, although phosphate is undoubtedly dominant in many systems, phosphorus compounds with lower oxidation states (reduced phosphorus) can also be present in the environment and could be of practical importance in many circumstances. Most reduced phosphorus compounds are likely to originate in steel-making or thermal phosphorus plants. It was determined that reduced phosphorus would not be detected in routine environmental analyses even if they were present. A new method was developed to detect these compounds, and in a preliminary survey reduced phosphorus was proven to be present in water that contacts corroding iron pipes, steel slag samples, phosphorus plant wastewater, phosphite fertilizers, and in sewage treatment plant effluent. However, no evidence could be obtained for massive bio-reduction of phosphates that has been proposed by some researchers. Given that phosphorus is often a limiting nutrient, and phosphorus compounds sometimes inhibit and sometimes catalyze practically important reactions (e.g. iron corrosion), future work should examine reduced phosphorus occurrence and chemistry in greater detail.
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