Title page for ETD etd-51798-143236

Type of Document Master's Thesis
Author Smith, Susan H.
Author's Email Address Susan_Smith@atk.com
URN etd-51798-143236
Title Extraction of Additives from Polystyrene and Subsequent Analysis
Degree Master of Science
Department Chemistry
Advisory Committee
Advisor Name Title
Taylor, Larry T. Committee Chair
Long, Gary L. Committee Member
Wolfe, James F. Committee Member
  • High Performance Liquid Chromatography
  • Supercritical Fluid Extraction
  • Polymer Additives
  • Polystyrene
Date of Defense 1998-06-11
Availability unrestricted

The extraction of fifteen (15) polymer additives with supercritical carbon dioxide which are used as antioxidants, uv stabilizers, process lubes, flame retardants and antistats from eight formulations of polystyrene is demonstrated and compared to traditional dissolution/precipitation extractions. The purpose of the study was twofold: 1) the development of a high performance liquid chromatography (HPLC) method(s) for the additives and 2) the determination of the viability of supercritical fluid extraction (SFE) for the additives from polystyrene. Separation of some of the additives was achieved using reversed phase liquid chromatography. Nine of the additives were assayed in this manner while, the remaining six additives could not be assayed using reversed phase liquid chromatography. In order to develop an extraction method for the additives, the effects of static extraction time, CO2 density, and temperature were first investigated. These preliminary extractions revealed that a static extraction period which afforded an opportunity for the polymer to swell combined with a high CO2 density and extraction temperature above the glass transition (Tg) yielded quantitative recoveries of the additives. Triplicate extractions of the various polystyrene formulations matched additive recoveries obtained by the traditional dissolution/precipitation method.

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