Title page for ETD etd-73197-10251

Type of Document Master's Thesis
Author Laot, Christelle Marie III
Author's Email Address claot@vt.edu
URN etd-73197-10251
Title Spectroscopic Characterization of Molecular Interdiffusion at a Poly(Vinyl Pyrrolidone) / Vinyl Ester Interface
Degree Master of Science
Department Chemical Engineering
Advisory Committee
Advisor Name Title
Marand, Eva Committee Chair
Davis, Richey M. Committee Member
Oyama, Hideko T. Committee Member
Ward, Thomas C. Committee Member
  • FTIR-ATR spectroscopy
  • diffusion
  • interface
  • interphase
  • vinyl ester
  • poly(vinyl pyrrolidone)
  • plasticization
Date of Defense 1997-08-25
Availability unrestricted
Mechanical properties of (woven carbon fiber / vinyl ester matrix) composites can be greatly improved if the interphase between the reinforcing high-strength low-weight fiber and the thermoset resin is made more compliant. In order to improve the adhesion of the vinyl ester matrix to the carbon fiber, a thermoplastic coating such as poly(vinyl pyrrolidone) (PVP) can be used as an intermediate between the matrix and the fiber. The extent of mutual diffusion at the (sizing material / polymer matrix) interphase plays a critical role in determining the mechanical properties of the composite.

In this research, the molecular interdiffusion across a poly(vinyl pyrrolidone))/vinyl ester monomer (PVP/VE) interface is being investigated by Fourier Transform Infrared Attenuated Total Reflectance (FTIR-ATR) spectroscopy. The ATR method which can be used to characterize the transport phenomena, offers several advantages, such as the ability to monitor the diffusion in situ or to observe chemical reactions. In order to separate the effects of the vinyl ester monomer diffusion and the crosslinking reaction, ATR experiments were carried out at temperatures below the normal curing temperature. Diffusion coefficients were determined by following variations in infrared bands as a function of time, and fitting this data to a Fickian model. The values of the diffusion coefficients calculated were consistent with values found in the literature for diffusion of small molecules in polymers. The dependence of diffusion coefficients on temperature followed the Arrhenius equation. Hydrogen bonding interactions were also characterized. The diffusion model used in this study, however, does not seem to be appropriate for the particular (PVP/VE) system. Because the glass transition temperature of the PVP changed as diffusion proceeded, one would expect that the mutual diffusion coefficient did not stay constant. In fact, it was shown that the Tg can drop by 140oC during the diffusion process. A more suitable model of the (PVP/VE) system should take into account plasticization, hydrogen bonding, and especially a concentration dependent diffusion coefficient. Further analysis is therefore needed.

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