Title page for ETD etd-04162009-113815

Type of Document Dissertation
Author Whelton, Andrew James
Author's Email Address awhelton@vt.edu
URN etd-04162009-113815
Title Advancing Potable Water Infrastructure through an Improved Understanding of Polymer Pipe Oxidation, Polymer–Contaminant Interactions, and Consumer Perception of Taste
Degree PhD
Department Environmental Engineering
Advisory Committee
Advisor Name Title
Dietrich, Andrea M. Committee Chair
Edwards, Marc A. Committee Member
Gallagher, Daniel L. Committee Member
Love, Brian J. Committee Member
Tanko, James M. Committee Member
  • infrastructure
  • Water
  • degradation
  • health
  • taste
  • polyethylene
  • pipe
  • polymer
Date of Defense 2009-04-02
Availability unrestricted
While more than 100 years of research has focused on removing acute and chronic health threats from water, substantially less study has focused on potable water infrastructure and water quality deterioration, monitoring technologies, and relationships between water taste and consumer health. These knowledge–gaps have left infrastructure users, owners, regulators, and public health professionals largely unaware of how premise and buried polymer water pipes deteriorate and sorb/ desorb organic contaminants during normal operations and following water contamination events. These knowledge–gaps also prevent infrastructure managers from producing drinking water that optimizes mineral content for both water taste and health benefits, and employing a monitoring tool capable of immediately detecting water contamination or equipment failures.

Research was conducted to address these challenges using analytical chemistry, environmental engineering, food science, polymer chemistry, public health, and material science principles. This work was enhanced by collaborations with sixteen American water utilities and the National Institute for Standards and Technology. These efforts were funded by the National Science Foundation, American Water Works Association, and the Water Research Foundation.

Research results are unique and provide important scientific contributions to the public health, potable water, and material science industries. Particular achievements include the: (1) Evaluation of linkages between minerals, water palatability, and health useful for water production and public health decisions; (2) Creation of a novel infrastructure and water quality surveillance tool that has begun water utility implementation in the USA; (3) Development of an accelerated chlorinated water aging method with stable water pH, free chlorine, and alkalinity concentration that enables interpretation of polymer pipe surface and bulk characteristic changes; (4) Discovery that polar compounds are 2–193% more soluble in PEX than HDPE water pipes; (5) Finding that several polymer and contaminant properties can be used to predict contaminant diffusivity and solubility during sorption and desorption in new, lab aged, and water utility PE pipes; and the (6) Discovery that chlorinated water exposure of HDPE and PEX pipes increases polar contaminant diffusivity during sorption by 50–162% and decreases diffusivity during desorption as much as 211%. Outcomes of this work have domestic and global significance, and if engaged, can greatly improve public health protection, potable water infrastructure operations, water quality, sustainability, and regulation.

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