Type of Document Dissertation Author Fratini, Christopher M. Author's Email Address email@example.com URN etd-04242006-105009 Title Study of the Morphology and Optical Properties of Propylene/Ethylene Copolymer Films Degree PhD Department Chemistry Advisory Committee
Advisor Name Title Marand, Hervé L. Committee Chair Esker, Alan R. Committee Member Gibson, Harry W. Committee Member Ward, Thomas C. Committee Member Wilkes, Garth L. Committee Member Keywords
- Light Scattering
- Surface Roughness
Date of Defense 2006-04-14 Availability unrestricted AbstractThe development of a new catalyst system by The Dow Chemical Company has resulted in the production of isotactic polypropylene and propylene/ethylene copolymers with a unique defect and comonomer distribution. This work investigated the morphology and optical properties of cast and compression molded films made from the homopolymer and copolymers with up to 20 mol% ethylene comonomer. The defect distribution of the Dow Chemical copolymers resulted in materials with lower crystallinity than Ziegler-Natta or metallocene-made materials of similar ethylene content. These materials exhibited a gamma-phase crystal content ranging from 0-95%, depending on ethylene content, processing condition, and catalyst type.
The gamma-phase crystal content of quiescently crystallized copolymer films was found to significantly influence their bulk optical properties, presumably through a change in the spherulite birefringence. The bulk haze, clarity, and transparency of a homopolymer film were degraded through annealing treatments, which decreased the fraction of gamma-phase crystallinity and increased the thickness of existing lamellae, resulting in an increased intensity of scattered light and a corresponding degradation in the optical properties of the film. The haze, clarity, transparency, and gloss of the copolymer films were found to improve at higher comonomer content and higher cooling rates. The variation in the length scale and degree of disorder in the bulk morphology of films processed under different conditions was shown to correlate with the optical quality of the films, with smaller scale morphologies scattering less light and resulting in films with better optical properties.
It was also shown that no single metric can completely describe the optical quality of a polymer film; the relative importance of haze, transparency, and gloss, which depends on the intended application of the film, was discussed. The influence of surface scattering from the films was controlled through the compression molding of films using substrates of different surface roughness. The contribution of light scattered from the surface of the films was isolated and found to play a significant role in the degradation of optical quality.
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